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article · Open Ceramics · 2023

Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization

Stephan A. Brinckmann, Jia Yao, Jason Young, Matthew Jones, Ray S. Fertig, Carl P. Frick

Cited by 15Open access

Abstract

The 3D printing of pre-ceramic polymers that can be pyrolyzed into functional ceramics has recently become a focus for advanced ceramic applications requiring complex geometries. In this work, a new methodology for 3D printing SiCNO ceramic materials derived from a novel pre-ceramic photopolymer feedstock utilizing a thiol-ene reaction is introduced. The printed parts are pyrolyzed to amorphous SiCNO and the physical and mechanical properties of the final ceramic are measured. Pyrolysis of the pre-ceramic produced a SiCNO ceramic with 41% ceramic yield and shrinkage of 24% with a hardness measured at 6.6 GPa ± 0.3 GPa.

Cite this paper

APA 7

Brinckmann, S. A., Yao, J., Young, J., Jones, M., Fertig, R. S., & Frick, C. P. (2023). Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization. Open Ceramics, 15, 100414. https://doi.org/10.1016/j.oceram.2023.100414

MLA 9

Brinckmann, Stephan A., et al. “Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization.” Open Ceramics, vol. 15, 2023, p. 100414, https://doi.org/10.1016/j.oceram.2023.100414.

Chicago

Brinckmann, Stephan A., Jia Yao, Jason Young, Matthew Jones, Ray S. Fertig, and Carl P. Frick. 2023. “Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization.” Open Ceramics 15: 100414. https://doi.org/10.1016/j.oceram.2023.100414.

Harvard

Brinckmann, S.A. et al. (2023) ‘Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization’, Open Ceramics, 15, p. 100414. Available at: https://doi.org/10.1016/j.oceram.2023.100414.

BibTeX
@article{brinckmann2023additive,
  title = {{Additive manufacturing of SiCNO polymer-derived ceramics via step-growth polymerization}},
  author = {Brinckmann, Stephan A. and Yao, Jia and Young, Jason and Jones, Matthew and Fertig, Ray S. and Frick, Carl P.},
  journal = {Open Ceramics},
  volume = {15},
  pages = {100414},
  year = {2023},
  doi = {10.1016/j.oceram.2023.100414}
}

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